Based on laboratory tests of selected properties of secondary waste (ashes and dusts) from municipal waste incineration plants, the possibility of recovering some properties of waste in the process of filling the post-mining voids in the salt mine was assessed. The furnace bottom ash and the waste from the flue gas treatment from one of the national incineration plants were examined. The grain curves of dry waste and the density of the prepared mixtures were characterized. Twelve variants of the compositions of ash-based mixtures with varying proportions of the individual components were considered, taking into account both fresh water and brine. For each variant of the composition, the amount of redundant liquid appeared as well as the time of solidifying of the mixture to a certain strength and the compressibility values obtained. Considering the possibility of transporting mixtures in mines by means of pipelines at relatively long distances, and allowing the filling of large salt chambers to be filled and evenly filled, flow parameters were determined. In addition, the permeability of solidified waste samples was investigated, showing the potential for reducing the strength of the waste mass due to the action of water or brine. The technical feasibility of eliminating redundant liquid in the binding process has been confirmed, which is particularly important in salt mines. Preliminary values for the amount of binder (5%÷10%) to be added to the mixtures to obtain the specified strength properties of the artificially formed mass at Rc = 0.5 MPa. Attention was paid to the important practical aspect resulting from the rapid increase of this type of waste in the comming years in Poland and at the same time vast potential for their use in salt mining, where we have a huge capacity of salt chambers available.
Strength and permeability properties along with microstructural evolution of hardened slurries composed of fly ash from fluidal bed combustion of brown coal and an addition of OPC/BFSC is assessed in this paper. An increase in the amount of fly ash in slurries influences the development of mechanical strength and a decrease of hydraulic conductivity. SEM, XRD, and porosity analyses confirmed formation of watertight microstructures. The structure of slurries is composed of ettringite, C-S-H phase, AFt, and AFm phases. Ettringite crystallises as relatively short needles forming compact clusters or intermixed with the C-S-H phase. The occurring C-S-H phases are mainly of type I – fibrous and type II – honeycomb
The numerical algorithm of thermal phenomena is based on the solution of the heat conduction equations in Petrov-Galerkin’s formula using the finite element method. In the modeling of phase transformation in the solid state, the models based on the diagrams of continuous heating and continuous cooling (CHT and CCT). In the modeling of mechanical phenomena, equations of equilibrium and constitutive relationships were adopted in the rate form. It was assumed that the hardened material is elastic-plastic, and the plasticizing can be characterized by isotropic, kinematic or mixed strengthening. In the model of mechanical phenomena besides thermal, plastic and structural strains, the transformations plasticity was taken into account. Thermo-physical size occurring in the constitutive relationship, such as Young’s modulus and tangential modulus, while yield point depend on temperature and phase composition of the material. The modified Leblond model was used to determine transformation plasticity. This model was supplemented by an algorithm of modified plane strain state, advantageous in application to the modeling of mechanical phenomena in slender objects. The problem of thermoelasticity and plasticity was solved by the FEM. In order to evaluate the quality and usefulness of the presented numerical models, numerical analysis of temperature fields, phase fractions, stresses and strains was performed, i.e. the basic phenomena accompanying surface layer of progressive-hardening with a movable heat source of slender elements made of tool steel for cold work.
Recently, some major changes have occurred in the structure of the European foundry industry, such as a rapid development in the production of castings from compacted graphite iron and light alloys at the expense of limiting the production of steel castings. This created a significant gap in the production of heavy steel castings (exceeding the weight of 30 Mg) for the metallurgical, cement and energy industries. The problem is proper moulding technology for such heavy castings, whose solidification and cooling time may take even several days, exposing the moulding material to a long-term thermal and mechanical load. Owing to their technological properties, sands with organic binders (synthetic resins) are the compositions used most often in industrial practice. Their main advantages include high strength, good collapsibility and knocking out properties, as well as easy mechanical reclamation. The main disadvantage of these sands is their harmful effect on the environment, manifesting itself at various stages of the casting process, especially during mould pouring. This is why new solutions are sought for sands based on organic binders to ensure their high technological properties but at the same time less harmfulness for the environment. This paper discusses the possibility of reducing the harmful effect of sands with furfuryl binders owing to the use of resins with reduced content of free furfuryl alcohol and hardeners with reduced sulphur content. The use of alkyd binder as an alternative to furfuryl binder has also been proposed and possible application of phenol-formaldehyde resins was considered.
The contributions of work-hardening of austenite and the presence of martensite on the hardening of an AISI 304L stainless steel were evaluated based on plastic deformation under different reductions in thickness at two rolling temperatures. The cold deformation temperatures of 300 K and 373 K were chosen to induce strain-hardening plus strain-induced martensitic transformation in the former and strain-hardening in the latter. This made it possible to elucidate the real effects of strengthening mechanisms of metastable austenitic stainless steels during mechanical working.
The paper presents the research results of the influence of the precipitation hardening on hardness and microstructure of selected Al-Si and Al-Cu alloys obtained as 30 mm ingots in a horizontal continuous casting process. The ingots were heat treated in process of precipitation hardening i.e. supersaturation with subsequent accelerated or natural ageing. Moreover in the range of the study it has been carried out investigations of chemical constitution, microscopic metallographic with use of scanning electron microscope with EDS analysis system, and hardness measurements using the Brinell method. On basis of obtained results it has been concluded that the chemical constitution of the investigated alloys enables to classify them into Al alloys for the plastic deformation as EN AW-AlSi2Mn (alternatively cast alloy EN AC-AlSi2MgTi) and as EN AW-AlCu4MgSi (alternatively cast alloy EN AC-AlCu4MgTi) grades. Moreover in result of applied precipitation hardening has resulted in the precipitation from a supersaturated solid solution of dispersive particles of secondary phases rich in alloying element i.e. Si and Cu respectively. In consequence it has been obtained increase in hardness in case of AlSi2Mn alloy by approximately 30% and in case of AlCu4MgSi alloy by approximately 20% in comparison to the as-cast state of continuous ingots.
The high mechanical properties of the Al-Li-X alloys contribute to their increasingly broad application in aeronautics, as an alternative forthe aluminium alloys, which have been used so far. The aluminium-lithium alloys have a lower specific gravity, a higher nucleation andcrack spread resistance, a higher Young’s module and they characterize in a high crack resistance at lower temperatures. The aim of theresearch planned in this work was to design an aluminium alloy with a content of lithium and other alloy elements. The research includedthe creation of a laboratorial melt, the microstructure analysis with the use of light microscopy, the application of X-ray methods to identify the phases existing in the alloy, and the microhardness test.
In view of the permanent increase of the municipal solid waste incineration (MSWI) residues amount, the numerous attempts to find a way of their recovery have been undertaken. In this paper the idea of the recovery of the MSWI residues in Kłodawa salt mine is presented. The idea is to fill the waste in underground workings, close and/or backfill the underground excavations with self-solidifying mixture prepared on the basis of MSWI grained solid residues. Two techniques are proposed: 1) hydraulic backfill technique (HBT) where the mixture is prepared in the surface installation and pumped down into the underground workings through shaft and the pipelines and 2) dry waste technique (DWT), where dry grained waste is dropped into the mine by pneumatic pipeline transport, then supplied to the underground mixture-preparing- installation and pumped as a thin liquid or paste into the selected workings. The description of the technology is preceded by general characteristic of the hardening backfill in underground mines and by characteristic of MSWI residues, drafted on the basis of the literature review.
Fuzzy logic determination of the material hardening parameters based on the Heyer’s method was applied in this research. As the fuzzy input variables, the length of two measuring bases and the maximum force registered in the Heyer’s test were used. Firstly, the numerical experiment (the simulation of the fuzzification of the input data) with the assumed disturbance of input variables was performed. Next, on the basis of experimental investigations (eleven samples made from the same material), the membership functions associated with the input data were created. After that, the fuzzy analysis was examined. Fuzzy material hardening constants obtained by means of the α-level optimization and the extension principle methods were compared. Discrete values of the hardening data are found in the defuzzification process, by application of the mass center method.
The results of mechanical reclamation of waste moulding sands with furfuryl resin and activators of new generation are presented. The aim of the research described in this study was to determine what effect the addition of reclaim obtained in the process of dry mechanical reclamation could have on the properties of furan sands. The sand supplied by one of the domestic foundries was after the initial reclamation subjected to a two-step proper reclamation process. The following tests were carried out on the obtained reclaim: pH, S and N content, loss on ignition and comprehensive sieve analysis. The obtained reclaim was next used as a component of moulding sands with furfuryl resin, wherein it formed 50% and 80% of the base moulding material, respectively. The strength properties of the ready sand mixtures (bending strength Rg u and tensile strength Rm u ) were determined after the hardening time of 0.5, 1, 2, 4 and 24 hours.
One type of spheroidal cast iron, with additions of 0.51% Cu and 0.72% Ni, was subjected to precipitation hardening. Assuming that the greatest increase in hardness after the shortest time of ageing is facilitated by chemical homogenisation and fragmentation of cast iron grain matrix, precipitation hardening after pre-normalisation was executed. Hardness (HB), microhardness (HV), qualitative and quantitative metalographic (LM, SEM) and X-ray structural (XRD) tests were performed. The acquired result of 13.2% increase in hardness after ca. 5-hour ageing of pre-normalised cast iron confirmed the assumption.
The article presents results of heat treatment on the high chromium cast iron. The study was carrying out on samples cut from the casting made from chromium cast iron. Those were hardened at different temperatures, then tempered and soft annealed. The heat treatment was performed in a laboratory chamber furnace in the Department of Engineering Alloys and Composites at Faculty of Foundry Engineering AGH. At each stage of the heat treatment the hardness was measured by Vickers and Rockwell methods, and the microscope images were done. Additionally based on images from the optical microscope the microstructure was assessed. Based on these results, the effect of hardening, tempering and soft annealing on the microstructure and hardness of high chromium cast iron was studied. Next the effects of different hardening temperatures on the properties of high chromium cast iron were compared. The study led to systemize the literature data of the parameters of heat treatment of high chromium cast iron, and optimal conditions for heat treatment was proposed for casts of similar properties and parameters.
This publication describes research on the course of the process of cross-linking new BioCo polymer binders - in the form of water-based polymer compositions of poly(acrylic acid) or poly(sodium acrylate)/modified polysaccharide - using selected physical and chemical factors. It has been shown that the type of cross-linking factor used influences the strength parameters of the moulding sand. The crosslinking factors selected during basic research make it possible to obtain sand strengths similar to those of samples of sands bonded with commercial binders. Microwave radiation turned out to be the most effective cross-linking factor in a binder-matrix system. It was proven that adsorption in the microwave radiation field leads to the formation of polymer lattices with hydrogen bonds which play a major role in maintaining the formed cross-linked structures in the binder-matrix system. As a result, the process improves the strength parameters of the sand, whereas the hardening process in a microwave field significantly shortens the setting time.
Grey cast iron belongs to materials for casting production, which have wide application for different industry branches. Wide spectrum of properties of these materials is given by the structure of base metal matrix, which can be influenced with heat treatment. Processes of annealing can be applied for grey cast iron without problems. During heat treatment processes, where higher cooling rates are used, the thermal and structural strains become important. Usage and conditions of such heat treatment for grey cast iron castings of common production are the subject of evaluation of this article.
The article takes into consideration the researches concerning inserting the Glassex additive to the microwaved-hardened and selfhardened moulding sands with water glass. In the research different types of ester hardeners to self-hardened moulding sands with water glass were used. The influence of Glassex additive on retained strength of moulding sands with different hardeners and prepared by different technologies of hardening were tested. The influence of different hardeners and the technology of hardening on retained strength of moulding sand with water glass and the Glassex additive were also estimated.
Measurements of the hardening process of the selected self-setting sands are presented in the hereby paper. Moulding sands were prepared on the matrix of „Szczakowa” sand of the Sibelco Company. Two resins: phenol-formaldehyde-furfuryl (FF/AF) and urea-formaldehydefurfuryl (MF/AF) were used for making moulding sands. – Methylbenzene-sulphonic acid was applied as a hardener for the moulding sand on FF/AF resin, while paratoluene-sulphonic acid for the moulding sand on MF/AF resin. Both hardeners were used in two concentrations: low – the so-called ‘slow’ hardener and high - ‘fast’ hardener. During investigations, the courses of the hardening process were determined, more accurately changes of the velocity of the ultrasound wave passage through the moulding sand cL = f(t) and changes of the moulding sand hardening degree versus time, Sx = f(t). In addition, the kinetics of the hardening process was determined. Measurements were performed on the research stand for ultrasound investigations.
Measurements of the hardening process course of the selected self-hardening moulding sands with the reclaimed material additions to the matrix, are presented in the hereby paper. Moulding sands were produced on the „Szczakowa” sand (of the Sibelco Company) as the matrix of the main fraction FG 0,40/0,32/0,20, while the reclaim was added to it in amounts of 20, 50 and 70%. Regeneration was performed with a horizontal mechanical regenerator capacity of 10 t/h. In addition, two moulding sands, one on the fresh sand matrix another on the reclaimed matrix, were prepared for comparison. Highly-fluid urea-furfuryl resin was used as a binder, while paratoluensulphonic acid as a hardener. During investigations the hardening process course was determined, it means the wave velocity change in time: cL = f(t). The hardening process kinetics was also assessed (dClx/dt = f(t)). Investigations were carried out on the research stand for ultrasound tests. In addition strength tests were performed.
The results of studies of W-Ni-Co-Fe experimental alloy, with chemical composition assuring a possibility of producing Ni-based supersaturated solid solution are presented. The alloy was prepared from tungsten, nickel, cobalt and iron powders which were first mixed then melted in a ceramic crucible where they slowly solidified in hydrogen atmosphere. Next specimens were cut from the casting and heated at a temperature 950o C. After solution treatment the specimens were water quenched and then aged for 20 h at a temperature 300o C. The specimens were subjected to microhardness measurements and structure investigations. The latter included both conventional metallography and SEM observations. Moreover, for some specimens X-ray diffractometry studies and TEM investigations were conducted. It was concluded that quenching lead to an increase of tungsten concentration in nickel matrix which was confirmed by Ni lattice parameter increase. Aging of supersaturated solid solution caused strengthening of the Ni-based matrix, which was proved by hardness measurements. The TEM observation did not yield explicit proofs that the precipitation process could be responsible for strengthening of the alloy.
In the paper, an attempt is made to explain the previously observed increased effectiveness of utilising hydrated sodium water-glass grade 137 after hardening moulding sands with selected physical methods. In the modified process of preparing sandmixes, during stirring components, water as a wetting additive was introduced to the sand-binder system. Presented are examination results of influence of faster microwave heating and slower traditional drying of the so-prepared moulding sands on their tensile and bending strength, calculated per weight fraction of the binder. The measurement results were confronted with SEM observations of linking bridges and with chemical analyses of grain surfaces of high-silica base. On the grounds of comprehensive evaluation of hardened moulding sands, positive effects were found of the applied physical process of binder dehydration and presence of the wetting additive. It was observed that introduction of this additive during stirring, before adding the binder, improves flowing the binder to the places where durable linking bridges are created. It was also found that the applied methods of hardening by dehydration enable creation of very durable linking bridges, strongly connected with the sand base, which results in damages of high-silica grain surfaces, when the bridges are destroyed.
This article presents test results for hydraulic conductivity and porosity structure of hardening slurries prepared of Portland cement, betonite, water and fluidal ashes from the combustion of hard and brown coal. The slurries were exposed to persistent filtering action (180 days) of liquids chemically aggressive to cement binders, i.e. distilled water, 0.5% solution of nitric acid, 1% solution of sodium sulphate, 1% solution of magnesium nitrate and 1% solution of ammonium nitrate. Samples exposed to filtration of tap water constituted the reference base. The research was into relations between hydraulic conductivity and pore structure parameters in slurries, as well as into the influence of the type of aggressive medium on leak tightness of slurries (their porosity and hydraulic conductivity).
This article presents ways of possible utilization and application of fl uidal combustion wastes as active additives to hardening slurries which are used to seal environment protection structures, i.e. cut-off walls in waste dumps and wastewater treatment plants. Cut-off walls are often exposed to fi ltrating action of eluates - polluted (aggressive) waters. Results of hydraulic conductivity tests of slurries after their long-term (210 days) fi ltration with eluates from a municipal waste dump and with tap water are presented. Porosity tests were also conducted to show the porosity structure of the fi ltered slurries. Additionally, compressive strength of slurries maturing in tap water and waste dump eluates was tested in parallel.
The presented in the paper investigations were aimed at the determination of the reclaimed material (obtained in the dry mechanical reclamation process) addition influence on properties of moulding sands with hydrated sodium silicate modified by colloidal suspension of zinc oxide nanoparticles in propanol. Nanoparticles originated from the thermal decomposition of alkaline zinc carbonate, were used. The results of the reclamation of the spent moulding sand with hydrated sodium silicate performed in the AT-2 testing reclaimer are presented in the paper. Both, spent sands from the Floster S technology and from the technology with the modified water-glass were subjected to the reclamation processes. The following determinations of the reclaimed material were performed: pH reaction, acid demand, ignition loss and Na2O content. The obtained reclaim was used as a matrix component of moulding sands with water-glass in the Floster S technology, in which it constituted 60% and 50% of the sand matrix. The strength properties of the prepared moulding sands were determined (bending strength Rg u , tensile strength Rm u ) after samples storing times: 1h, 2h, 4h and 24 hours.
The necessity of obtaining high quality castings forces both researchers and producers to undertake research in the field of moulding sands. The key is to obtain moulding and core sands which will ensure relevant technological parameters along with high environmental standards. The most important group in this research constitutes of moulding sands with hydrated sodium silicate. The aim of the article is to propose optimized parameters of hardening process of moulding sands with hydrated sodium silicate prepared in warm-box technology. This work focuses on mechanical and thermal deformation of moulding sands with hydrated sodium silicate and inorganic additives prepared in warm-box technology. Tested moulding sands were hardened in the temperature of 140oC for different time periods. Bending strength, thermal deformation and thermal degradation was tested. Chosen parameters were tested immediately after hardening and after 1h of cooling. Conducted research proved that it is possible to eliminate inorganic additives from moulding sands compositions. Moulding sands without additives have good enough strength properties and their economic and ecological character is improved.
Modern techniques of castings production, including moulding sands production, require a strict technological regime and high quality materials. In the case of self-hardening moulding sands with synthetic binders those requirements apply mainly to sand, which adds to more than 98% of the whole moulding sand mixture. The factors that affect the quality of the moulding sands are both chemical (SiO2 , Fe2O3 and carbonates content) and physical. Among these factors somewhat less attention is paid to the granulometric composition of the sands. As a part of this study, the effect of sand quality on bending strength Rgu and thermal deformation of self-hardening moulding sands with furfural and alkyd resin was assessed. Moulding sands with furfural resin are known  to be the most susceptible to the sand quality. A negative effect on its properties has, among others, high content of clay binder and so-called subgrains (fraction smaller than 0,1mm), which can lead to neutralization of acidic hardeners (in the case of moulding sands with furfuryl resin) and also increase the specific surface, what forces greater amount of binding agents. The research used 5 different quartz sands originating from different sources and characterized with different grain composition and different clay binder content.