Natural gas combustion was carried out in air enriched with oxygen in the amount of 25 and 29% with addition of CO2 in place of part of nitrogen. The research was carried out at different flow rates of gas and oxygen excess ratios. The concentration of CO and NOx was analyzed. It has not been proved that the increased oxygen concentration influences significantly the CO concentration. However, the addition of CO2 caused a substantial variability of CO concentration in the exhaust gas, in contrast to the concentration of NOx which decreased monotonically. Model calculations, performed with use of FactSage, indicate an increase in the concentration of CO not only for the air enriched with oxygen, but after adding CO2 too, as well
Emission of gases under high temperature after pouring molten metal into moulds, which contain the organic binder or other additives (solvents or curing agent), may be an important factor influencing both on the quality of the produced castings, and on the state of environment. Therefore, a comprehensive study of the emitted gases would allow to determine restrictions on the use of the moulding sands in foundry technologies, eg. the probability of occurrence of casting defects, and identify the gaseous pollutants emitted to the environment. The aim of the research presented in this paper was to determine the amount of gases that are released at high temperatures from moulding sands bonded by biopolymer binder and the quantitative assessment of the emitted pollutants with particular emphasis on chemical compounds: benzene, toluene, ethylbenzene and xylenes (BTEX). The water-soluble modified potato starch as a sodium carboxymethyl starch with low (CMS-NaL) or high (CMS-NaH) degree of substitution was a binder in the tested moulding sands. A tests of gases emission level were conducted per the procedure developed at the Faculty of Foundry Engineering (AGH University of Science and Technology) involving gas chromatography method (GC). The obtained results of the determination of amount of BTEX compounds generated during the decomposition process of starch binders showed lower emission of aromatic hydrocarbons in comparison with binder based on resin Kaltharz U404 with the acidic curing agent commonly used in the foundries.
The work contains a description of a developed experimental and theoretical method of modeling of solid waste combustion in a device equipped with a moving grate and capability to optimize the work of waste incineration plant. Implementation of this issue was based on results of experimental studies made on a laboratory scale boiler. This was possible by defining and testing indicators of quantitative assessment of combustion such as: reaction front rate, ignition rate, the rate of combusted mass loss and the heat release rate. These indicators as measurable "criteria indicators" allow transfer of parameters from a laboratory-scale unit, working in the transient regime into an industrial full scale grate device working continuously in stable determined conditions. This allows for wide optimization possibilities in the operation of a waste incineration plant, in particular the combustion chamber, equipped with a moving grate system.
Gas emission from casting moulds, cores and coatings applied for sand and permanent moulds is one of the fundamental reasons of casting defects occurrence. In the previous studies, gas emission was measured in two ways: normalized, in which the evolving gas volume was measured during heating of the moulding sand sample in a sealed flask, or by measuring the amount of gas from sand core (sample) which is produced during the pouring of liquid metal. After the pouring process the sand mould is heated very unequally, the most heated areas are layers adjacent to the liquid metal. The emission of gas is significantly larger from the surface layer than from the remaining ones. New, original method of measuring kinetics of gas emission from very thin layers of sand moulds heated by liquid metal developed by the authors is presented in the hereby paper. Description of this new method and the investigation results of kinetics of gas emission from moulding sand with furan and alkyd resin are shown. Liquid grey cast iron and Al-Si alloy were used as a heat source in the sand moulds. Comparison of the kinetics of gas emission of these two kinds of moulding sands filled with two different alloys was made. The momentary metal temperature in sand mould was assigned to the kinetics of gas emission, what creates a full view of the possibility of formation of casting defects of the gaseous origin. Moulding sand with alkyd resin is characterized by larger gas emission; however gases are emitted slower than in the case of moulding sands with furan resin. This new investigation method has a high repeatability and is the only one which gives a full view of phenomenon’s in the surface layer which determines quality of the casings. The obtained results are presented on several graphs and analyzed in detail. They have a great application value and can be used in the production of iron as well as light metal alloy castings.
Biomass is commonly considered as a renewable fuel, which taking into account emission of CO2 does not contribute to the emission of the greenhouse gases. In the research, combustion tests of two types of fuel formed on the basis of straw with addition of polyethylene were performed in the laboratory. The article presents results of measurements of gas pollution coming from the combustion of the formed fuel. Obtained results were compared with similar literature data for the combustion of coal. The research covers also testing of chemical content, content of heavy metals and selected physical properties of ashes generated during the process of burning fuel based on straw.
Manual measurements of distribution of gas velocity in conduits of flue gas installations using systems with differential pressure sensors of velocity are often performed for the requirements of determining emissions of dust pollutants from industrial process plants to the atmosphere. The aim is to determine an axial velocity profile. Flows in measuring sections are not always coaxial along the run of the duct; they are characterized by different directions of the velocity vector at various measuring points. The determination of actual directions of vectors of local velocities giving a guarantee of an accurate calculation of the axial velocity is often not possible from the technical point of view and the measurement of the velocity is carried out with the parallel setting of the sensor head in relation to the axis and the walls of the conduit. Then the knowledge of the directional sensitivity of the applied velocity sensor allows either to eliminate the axial velocity measurement error or to take it into account by the uncertainty of this measurement. For specific situations of two-dimensional variation of direction of the velocity vector, the directional sensitivity characteristics and in consequence the characteristics of error have been determined for three sensors adopted to tests: a zero pressure dust sampling probe with the anemometric function as an element of the gravimetric dust sampler and comparatively - two commonly used Pitot tubes: types S and L.
A forecast of the negative impact exerted on the environment by selected trace elements in “Bełchatów” Power Plant has been prepared on the basis of the results of investigations into these elements’ distribution carried out as part of earlier research on coal from “Bełchatów” Field and the data on updated analyses of the content of these elements in 55 brown coal samples from test boreholes. Work in “Bełchatów” Power Plant, which is supplied with coal from “Szczerców” Field, will be accompanied by trace elements transfer. On the basis of the conducted investigations it has been found that the biosphere is most threatened by mercury emissions. As shown by the presented results of analyses and calculations, the emissions of mercury in “Bełchatów” Power Plant are low. Mercury is accumulated chiefl y in gypsum produced in the FGD plant. The content of mercury in slag and ash is low.