The δ18O data for the last 8000 years in the Greenland NGRIP1, GRIP, DYE-3 and GISP2 ice cores have been analyzed stratigraphically in search of potentially meaningful boundaries and units. Pattern matching of the profiles is supported by using graphical display enhancements, calculating spectral trend curves and generating a compound profile. Techniques routinely used in subsurface geology have been applied in correlating the profiles. Four major stratigraphic units are identified (8.1–4.9, 4.9–3.3, 3.3–1.9 and 1.9–0.1 ka b2k), resulting in an improved understanding of the climate change after the Holocene Climate Optimum. Correlatable higher-order boundaries are identified within these units. The layers between the boundaries show δ18O patterns which generally are similar in character, the differences being ascribed to lateral variations in the factors that control the isotope content of the ice. The layering forms a series of short-lived low-amplitude aperiodic oscillations on a centennial time scale. The suggestion is that these higher-order boundaries and δ18O oscillations have climatic significance. Equivalent units are tentatively identified in ice-core data from the Agassiz and Renland ice caps. Comparison with other climate proxies or stratigraphies from the Northern Hemisphere is expected to render support for the here proposed scheme. It will then serve to guide and constrain the analysis of the dynamics of the climatic fluctuations for the study period.
The results of model investigations of the influence of the blowing process selected parameters on the distribution of the compaction of the core made by the blowing method, are presented in the hereby paper. These parameters were: shooting pressure, shooting hole diameter, amount and distribution of deaerating holes. Investigations were performed using the horizontal core box of the cuboidal cavity and the same core box into which inner inserts were introduced. These inserts were dividing the primary volume into three sectors differing in their direction, introduction conditions and the character of the core sand flow. As the compaction measure the apparent sand density was assumed. The density was determined in five measuring points in case of uniform cores, and in three measuring points in case of cores obtained in the core box with three separated sectors. The apparent density of the compacted core sand in the core box cavity was determined on the basis of the measurements of masses and volumes of samples cut-out from the determined core places by means of the measuring probe. Investigations were performed at three values of the working pressure equal 0.4, 0.5 and 0.6MPa for two diameters of the shooting hole: 10 and 20 mm. During tests the core box deaeration, controlled by an activisation of the determined number of deaerating vents placed in the core box, was also subjected to changes.
The results of investigations of sand shooting into the core box are presented in the hereby paper. The investigations concern the formation of the diphase sand-air flux, its motion, flowing and compaction in the cavity during the core forming. Conditions deciding on the course of individual phases of the process are discussed with taking into consideration the influence of such factors as: the shot pressure, shooting hole diameter, number and distribution of deaerating vents in experimental core boxes (of a single cavity and of multi cavities) on the core sand compaction state. Investigations were performed by means of the modernised experimental shooting machine SR-3D, of the shooting chamber volume of 3.3 dm3, connected with the system of pneumatic supply ensuring the stable pressure supply of values: 0.4 MPa, 0.5 MPa and 0.6 MPa. Two diameters of the shooting hole, equal 10 mm and 20 mm, were applied for filling three experimental core boxes differing in dimensions of cavities and in number and distribution of deaerating vents. The filling process of core boxes was recorded by means of the digital camera PHANTOM V210 with the filming rate of 3000 pictures in second. Simultaneously, during the shot, other values allowing to determine the intensity of the core sand outflow from the shooting chamber to the core box, were tested. The presented in this publication results constitute the important element of the experimental verification of the blowing process simulation calculations which will be performed.
The main relief features of glacier marginal zones in the region between the Billefjorden and Austfjorden comprise ice-cored moraines, outwash plains and glacial lakes. Characteristics of various types of ice-morainic ridges are given. This article presents examples of outwash fan relief. The results of palaeogeographical analysis serve as the basis for distinguishing between three principal stages of development of glacier morphology and meltwater outflow in the region between the Billefjorden and Austfjorden.
Over the past few years, a great deal of research has been conducted concerning the mathematical skills of children after the first stage of education. In my report, I present a selection of results from this research in order to illustrate the most typical didactical effects of the style in which mathematical education is performed in our schools. Comparing some detailed results from research in a number of chosen fields, I also try to assess whether or not, and how, the level of schoolchildren’s skills has changed in the recent years.
The investigation results of the mechanical reclamation of spent moulding sands from the Cordis technology are presented in the paper. The quality assessment of the obtained reclaim and the influence of the reclaim fraction in a matrix on the core sand strength is given. The reclaim quality assessment was performed on the basis of the determination of losses on ignition, Na2O content on reclaim grains and pH values. The reclaim constituted 100%, 75% and 50% of the core sand matrix, for which the bending strength was determined. The matrix reclamation treatment was performed in the experimental rotor reclaimer RD-6. Spent sands were applied in as-delivered condition and after the heating to a temperature of 140 o C. Shaped samples for strength tests were made by shooting and hardening of sands in the warmbox technology.
The paper presents the results of preliminary research on the use of silica sands with hydrated sodium silicate 1.5% wt. of binder for the performance of eco-friendly casting cores in hot-box technology. To evaluate the feasibility of high quality casting cores performed by the use of this method, the tests were made with the use of a semiautomatic core shooter using the following operating parameters: initial shooting pressure of 6 bar, shot time 4 s and 2 s, core-box temperature 200, 250 and 300 °C and core heating time 30, 60, 90 and 150 s. Matrixes of the moulding sands were two types of high-silica sand: fine and medium. Moulding sand binder was a commercial, unmodified hydrated sodium silicate having a molar module SiO2/Na2O of 2.5. In one shot of a core-shooter were made three longitudinal samples (cores) with a total volume of about 2.8 dm3. The samples thus obtained were subjected to an assessment of the effect of shooting parameters, i.e. shooting time, temperature and heating time, using the criteria: core-box fill rate, bending strength (RgU), apparent density and surface quality after hardening. The results of the trials on the use of sodium silicate moluding sands made it possible to further refine the conditions of next research into the improvement of inorganic warm-box/hot-box technology aimed at: reduction of heating temperature and shot time. It was found that the performance of the cores depends on the efficiency of the venting system, shooting time, filling level of a shooting chamber and grains of the silica matrix used.
Core sands for blowing processes, belong to these sands in which small amount of the applied binding material has the ability of covering the sand matrix surface in a way which - at relatively small coating thickness - allows to achieve the high strength. Although the deciding factor constitute, in this aspect, strength properties of a binder, its viscosity and ability to moisten the matrix surface, the essential meaning for the strength properties of the prepared moulding sand and the mould has the packing method of differing in sizes sand grains with the coating of the binding material deposited on their surfaces. The knowledge of the influence of the compaction degree of grains forming the core on the total contact surface area can be the essential information concerning the core strength. Forecasting the strength properties of core sands, at known properties of the applied chemically hardened binder and the quartz matrix, requires certain modifications of the existing theoretical models. They should be made more realistic with regard to assumptions concerning grain sizes composition of quartz sands and the packing structure deciding on the active surface area of the contacts between grains of various sizes and - in consequence - on the final strength of cores.
Analysis of the use of the Russian materials (liquid glass and softening additives) has been made in accordance with the modern requirements for use in the technological processes of casting as binding materials in the production of large-sized steel railway casting. The reasons for poor knockout of liquid glass mixtures have been investigated. A complex action softening additive has been recommended for a better knocking-out ability. This solution provides a softening effect at the points of maximum formation of the liquid glass matrix strength in the processes of polymorphic transformation of the material under the influence of elevated temperatures as the result of filling the mold cavity by the melt. It has been shown that the use of additives of complex action leads to the decrease in the specific work of the knockout by four – seven times depending on the composition of the mixture and the design features of the casting. Experimental-industrial tests of the proposed method for softening the liquid glass mixtures have been made and the "Front Buffer Stop" casting has been made (for the rolling stock of locomotives and railway wagons). The tests confirmed the effectiveness and expediency of implementation of new liquid glass mixtures with softening additives in conditions of foundry enterprises.
In the definition of civic competences which is situated in the Annex to Recommendation of the European Parliament and of the Council of 18 Decem-ber 2006 on key competences for lifelong learning – Key Competences for Life-long Learning – a European Reference Framework it is written: “Full respect for human rights including equality as a basis for democracy, appreciation and understanding of differences between value systems of different religious or ethnic groups lay the foundations for a positive attitude”. Therefore, the question is: Does school education in general premise developing attitudes based on val-ues essential to democracy? The answers to this question can be searched con-ducting various studies. The paper presents the results of analysis of the core curricula conducted by a team of researchers from the Department of School Education, Faculty of Educational Sciences, Nicolaus Copernicus University in Torun (Poland). Why core curricula have become the object of our research? Basically, for two reasons. Firstly, the school has obligated to implement them, and all school programs and textbooks have to be consistent with them. Second-ly, they are also a kind of articulation and a declaration of competence required from people in the given place and time.
The paper presents the solutions, calculation results and dynamic observations of three-layers, annular plate with thick core subjected to increasing in time load. The presented solutions use approximate methods: orthogonalization method and finite difference method in analytical and numerical solution of the problem, and finite element method. The observed phenomenon of the reduction of critical load values of the plates, in which the buckling mode is not global and there are different additional deflections of respective plate layers was comprehensively analysed in order to evaluate the critical state and supercritical plate behaviour. The critical deformation could have a form with strong deformation in the region of the loaded plate edge. The observation of the dynamic behaviour of plates, which buckling modes have circumferential waves is an important element of the analysis. Presented in this work the analytical and numerical solution to the problem of dynamic plate deflection was generalized on the case of plates with buckling waves in circumferential direction.
The article deals with the gas development of the geopolymer binder system hardened by heat and provides the comparison with organic binder systems. The GEOPOL® W technology is completely inorganic binder system, based on water. This fact allow that the gas generated during pouring is based on water vapour only. No dangerous emissions, fumes or unpleasant odours are developed. The calculated amount of water vapour generated from GEOPOL® W sand mixture is 1.9 cm3/g. The measured volume of gas for GEOPOL® W is 4.3 cm3/g. The measurement of gas evolution proves that the inorganic binder system GEOPOL® W generates very low volume of gas (water vapour) in comparison with PUR cold box amine and Croning. The amount of gas is several times lower than PUR cold box amine (3.7x) and Croning (4.2x). The experiment results are consistent with the literature sources. The difference between the calculated and the measured gas volume is justified by the reverse moisture absorption from the air after dehydration during storing and preparing the sand samples. Minimal generated volumes of gas/water vapour brings, mainly as was stated no dangerous emissions, also the following advantages: minimal risk of bubble defects creation, the good castings without defects, reduced costs for exhaust air treatment, no condensates on dies, reduced costs for cleaning.
The paper refers to earlier publications of the author, on identification of properties of thermomechanical, chemically hardened core/mold sands. In that earlier period, first version of the original DMA apparatus, produced by a Polish company Multiserw-Morek, was used. The Hot Distortion (HD) study results, published by the author in 2008, referred to phenomena accompanying a thermal shock in real conditions of thermal interaction of a liquid alloy on a mold, in reference to a shock possible to obtain in laboratory conditions, without use of liquid alloy as a heat source, with analysis of solutions applied in the DMA apparatus. This paper presents author’s observations on testing a new, innovative version of the LRu-DMA apparatus, containing a module allowing the Hot Distortion (HD) study. Temperature of specimens achieved in the case of the gas burner heating reaches values definitely above 800°C on the heated side and 610°C on the other side. Using an electric radiator, with maximal temperature of 900°C allows obtaining temperatures in between 225-300°C.
Mechanization of the process of core making with the use of inorganic and organic binders is based, almost solely, on core blowing machines. Presently the core blowing machines are equipped with tools and devices that allow for application of different technologies of core making. Cold-box, hot-box and warm-air technologies require that core blowing machines shall be additionally equipped with either core-box pre-heating system or gas purging and neutralization system, or hot air purging systems. Considering the possibility of using varied, the most advantageous technologies of core making, the production of universal core blowing machines equipped with replaceable devices has been undertaken in Poland. The universal core blowing systems allow for mechanization of core making process also with the use of sand, bonded by modern, eco-friendly binder systems. The paper presents selected results-based evaluation of core blowing process showing the scope of conducted design and implementation works.
The paper presents dynamic responses of annular plate composed of three layers. The middle layer of the plate has electrorheological properties expressed by the Bingham body model. The plate is loaded in the plane of facings with time-dependent forces. The electrorheological effect is observed in the area of supercritical plate behaviour. The influence of both material properties and geometrical dimensions of the core on plate behaviour is examined. The problem is solved analytically and numerically using the orthogonalization method and the finite difference method. Comparison of the results obtained using the finite difference and the finite element methods for a plate in critical state is shown. The numerical calculations are carried out for axisymmetric and asymmetric plate modes. The presented diagrams show the plate reaction to the changes in values of plate parameters and indicate that the supercritical control of plate work is possible.
In this study, rubber seed/shea butter oil was used to formulate core oil. The formulated core oil was characterised. D-optimal mixture design was used for multi response optimisation of the functional properties of rubber seed-shea butter coil oil. Desirable values for some responses might be obtained from a factor combination while for others responses not so desirable values. Through multiple response optimisations, a factor setting that gives the desirable values for all responses was obtained. The selected optimum mixture setting for the formulated core oil is 65.937% Rubber seed and 34.063% Shea butter oil at desirability of 0.924. Under the optimum condition the functional properties of the core oil was found to be 39.57KN/M2, 626.85KN/M2, 36.63KN/M2, 593.906KN/M2, 412.605 and 167.309s for Green Compressive Strength, Dry Compressive Strength, Green Tensile Strength, Dry Tensile Strength, Permeability and Collapsibility respectively. The optimum conditions were validated with less than 0.2% error. The functional properties of the formulated core oil was compared to the functional properties of linseed core oil. It was found that rubber seed-shea butter core oil can be used for producing cores suitable for Aluminium casting.
The results of investigations of the influence of the matrix grain sizes on properties of cores made by the blowing method are presented in the hereby paper. Five kinds of matrices, differing in grain size compositions, determined by the laser diffraction method in the Analysette 22NanoTec device, were applied in investigations. Individual kinds of matrices were used for making core sands in the Cordis technology. From these sands the shaped elements, for determining the apparent density of compacted sands and their bending strength, were made by the blowing method. The shaped elements (cores) were made at shooting pressures being 3, 4 and 5 atn. The bending strength of samples were determined directly after their preparation and after the storing time of 1 hour.
This article presents measurements of the thickness of alcohol-based coatings on sand foundry cores and moulds. These coatings were applied using two methods, the dipping method and the painting method. For the purposes of the study, a zircon alcohol-based coating was prepared with three different levels of nominal viscosity; very thin at 10s, average at 20s, and thick at 30s. The coating was applied to a core made of quartz sand and furan resin. The cores were made of sand with three different grain sizes; dL = 0.22 mm – fine sand, dL = 0.33 mm medium sand, and dL = 0.47 mm coarse sand. In the study, the thickness of the coating obtained to the core was measured immediately after application as well as after drying. Additionally, the extent of penetration into the intergranular spaces of the core matrix was measured. On the basis of this study, the impact of the grain size of the core matrix on the thickness of the coating and its penetration into the core was assessed. The thickness of coatings obtained using different application methods was also assessed.
Skeleton castings macrostructure can be shaped in many ways, by choosing an appropriate material of cores and manufacturing technologies. Important factor, which puts foundry techniques over the other technologies of periodic cellular materials, is ability to adjust mechanical properties by changing the microstructure of an alloy from which the casting is made. The influence on the microstructure of the skeleton casting can be implemented by choosing the thermal properties, mainly thermal conductivity factor, of mould and core materials. Macro- and microstructure of skeleton castings with octahedron elementary cells was presented in this paper. The analysis concerns the differences in morphology of eutectic silicone depending on the location of measurements cross sections areas. The use of thermo-insulating material with appropriate properties assures correct fill of mould cavity and homogeneous microstructure on whole volume of skeleton casting. The selection of technological parameters of the casting process if very important as well.
The paper presents the results of analyzes of gases emitted during exposure to high temperature foundry molding sands, where binders are organic resins. As a research tool has been used special gas chromatograph designed to identify odorous compounds including the group of alkanes.
The use of environmentally friendly inorganic binders and new technologies for cores production is widely discussed topic in recent years. This paper contains information about new hot curing process for core making with alumina-silicate based inorganic binders – geopolymers. Main differences between hot cured geopolymers and hot cured alkali silicate based inorganic binders are discussed. The main objective of this research paper was to investigate basic technological properties of geopolymer binder system such as strength, compaction, storage ability and knock-out properties. For this purpose, three mixtures with different powder additives were prepared and tested in laboratory conditions using specific methods. Strength properties evaluation showed sufficient levels as well as knock-out properties measurement, even with additives B and C originally designed for the use with alkali silicate based two component binder systems. Additives B and C were considered compatible with geopolymer binders after casting production trial results. Storage ability of geopolymers seems to be more sensitive than of alkali silicate based binders in the same tested conditions. Mixtures with geopolymer binder showed 20% more decrease of strength compared to alkali silicate binders after 24 hours in conditions of 25 °C and 65 %RH.
This paper deals with the complete technology of inorganic geopolymer binder system GEOPOL® which is a result of long term research and development. The objective of this paper is to provide a theoretical and practical overview of the GEOPOL® binder system and introduce possible ways of moulds and cores production in foundries. GEOPOL® is a unique inorganic binder system, which is needed and welcomed in terms of the environment, the work environment, and the sustainable resources. The GEOPOL® technology is currently used in the foundries for three basic production processes/technologies: (1) for self-hardening moulding mixtures, (2) sand mixtures hardened by gaseous carbon dioxide and (3) the hot box technology with hot air hardening. The GEOPOL® technology not only solves the binder system and the ways of hardening, but also deals with the entire foundry production process. Low emissions produced during mixing of sand, moulding, handling, and pouring bring a relatively significant improvement of work conditions in foundries (no VOCs). A high percentage of the reclaim sand can be used again for the preparation of the moulding mixture.
The paper presents a modification of capillary optical fibers fabrication method from an assembled glass preform. A change of dimensional proportions in the capillary optical fiber drawn from a single preform is allowed on-line via the control of overpressure and thermal conditions in the outflow meniscus which essentially lowers the manufacturing costs. These conditions are among the solutions (velocity fields) of the Navier-Stokes equations adapted to the capillary optical fiber pulling geometry and temperature distribution in the oven. The velocity fields give solutions to other quantities of interest such as flow rate, pulling force and fiber geometry. The calculation and experimental results for capillary optical fibers were shown in the following dimensional range: internal diameters 2-200 µm, external diameters 30-350 µm, within the assumed dimensional stability (including ellipticity) better than 1%. The parameters of fabricated capillary optical fibers of high-quality low-loss optical multicomponent glasses were: losses 100 dB/km, mechanical strength above 1GPa with Weibull coeffcient in the range 3-7, internal numerical aperture 0.1-0.3, external numerical aperture 0.1-0.3, core index 1.5-1.8, transparency 0.4-2 µm, thermally and/or chemically conditioned internal surface, double polyimide protection layer, soft or hard jacketed, connectorized. The capillary optical fibers were applied in our own and several external laboratories in spectroscopy, refractometry, micro-fluidics and functional microoptic components. The paper summarizes a design, technological and application work on capillary optical fibers performed during a recent national research program devoted to optoelectronic components and modules.
This paper outlines a measurement method of properties of microstructured optical fibers that are useful in sensing applications. Experimental studies of produced photonic-crystal fibers allow for a better understanding of the principles of energy coupling in photonic-crystal fibers. For that purpose, fibers with different filling factors and lattice constants were produced. The measurements demonstrated the influence of the fiber geometry on the coupling level of light between the cores. For a distance between the cores of 15 μm, a very low level (below 2%) of energy coupling was obtained. For a distance of 13 μm, the level of energy transfer to neighboring cores on the order of 2-4% was achieved for a filling factor of 0.29. The elimination of the energycoupling phenomenon between the cores was achieved by duplicating the filling factor of the fiber. The coupling level was as high as 22% in the case of fibers with a distance between the cores of 8.5 μm. Our results can be used for microstructured-fiber sensing applications and for transmission-channel switching in liquid-crystal multi-core photonic fibers.