In this paper are presented results of study fusion characteristics of the biomass ashes from the hydrolyzed lignin and the ashes from the coke breeze. The hydrolyzed lignin ashes were compared with the coke breeze ashes i.e. with a fossil fuel. These ashes were prepared in muffle furnace at the temperature of 550°C (hydrolyzed lignin) and 850°C (coke breeze). Biomass (the hydrolyzed lignin) represents the new fuels for sintering process and an attractive way to decrease CO2 emissions from the energy production. The characterization methods were the following: standard fuel characterization analyses, chemical and mineralogical composition of the ashes and phase analyses of the ashes of biomass and the coke breeze. These ashes were prepared by the same method. Characterisation of the ashes samples was conducted by means of X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Quantitative analysis of the crystalline and amorphous phases in each of the ash samples were carried out using the Rietveld method. The dominant phase of the ash from the coke breeze was mullite (Al6Si2O13). SiO2 is the dominant phase of the ash from the hydrolyzed lignin.
Currently is the biggest problem of metallurgical companies the increase of fossil fuel prices and strict environmental regulations. As a result of this, companies must look for alternatives that would reduce the amount of fossil fuels and reduce emissions. Wood sawdust has huge energy potential, which can be used in the process of agglomerate production. This type of energy is locally available, has some similar properties as fossil fuels and is economically advantageous. For these reasons, experimental study using laboratory agglomeration pan was realized to study the possibility of agglomerate production with a mixed fuel. Experimental results show the viability of mixed fuel use in the agglomeration process, but also show significant possibility for improvement. The maximum acceptable substitution ratio, which corresponds to qualitatively suitable agglomerate is 20% of pine sawdust. Based on the realized experiments and the obtained results we have acceded to the intensification of the agglomeration process with an objective to increase the amount of added substitution fuel while maintaining the required quality of agglomerate.