The author analyses onymic practices of Poznań–based craftsmen forming guilds. In the names of the inhabitants of Poznań, which stabilised until the end of the 18th century, she seeks traces of the so-called cognomens, i.e. secondary personal designations granted to apprentices who were becoming masters. The names resulted from community acts of creation, which were of ludic nature. Referring to German onymic practices and pointing to the so-called Schleifnamen, the author discusses specific codes of European middle-class culture. She focuses on the transfer of models and patterns to Polish urban communities.
The aim of the article is to analyse the spread and diffusion of socio-economic development in Poland in 2004-2016, while considering spatial aspects. Using the linear ordering method in the non-pattern version, a synthetic development measure for all municipalities in Poland was built based on a set of 77 features illustrating various socio-economic aspects, reduced to 25 features. For the measure constructed in this way, the convergence of the beta and sigma type has been examined, divided into 3 groups of municipalities (rural, urban and urban-rural), as well as in regional division. Using the methods of spatial econometrics, the occurrence of spatial effects was examined, in particular the attention was paid to the relationship between the processes of spreading development and spatial forms of diffusion of development. The analysis also allowed to determine the strength of local impacts of spatial connections between individual municipalities.
The effective diffusivity of water in brown coal of Bełchatów mine was experimentally determined. The experiments were performed in superheated steam at 200°C and atmospheric pressure using slightly compressed pellets of cylindrical shape. The drying and temperature curves of the sample were used to identify diffusivity. An inverse problem was formulated and solved by the finite element method for 3D axially symmetric cylindrical geometry of the sample. A satisfactory fit of the simulated curves to experimental results was obtained. The obtained dependence of effective diffusivity on moisture content and temperature may be used in designing lignite dryers.
Fabrication and microstructure of the AlSi11 matrix composite containing 10 % volume fraction of CrFe30C8 particles were presented in this paper. Composite suspension was manufactured by using mechanical stirring. During stirring process the temperature of liquid metal, time of mixing and rotational speed of mixer were fixed. After stirring process composite suspension was gravity cast into shell mould. The composites were cast, applying simultaneously an electromagnetic field. The aim of the present study was to determine the effect of changes in the frequency of the current power inductor on the morphology of the reinforcing phase in the aluminum matrix. The concept is based on the assumption that a chromium-iron matrix of CrFe30C8 particles dissolves and residual carbide phases will substantially strengthen the composite. The microstructure and interface structure of the AlSi11/CrFe30C8 composite has been studied by optical microscopy, scanning microscopy and X-ray diffraction.
The presence of more than one solute diffused in fluid mixtures is very often requested for discussing the natural phenomena such as transportation of contaminants, underground water, acid rain and so on. In the paper, the effect of nonlinear thermal radiation on triple diffusive convective boundary layer flow of Casson nanofluid along a horizontal plate is theoretically investigated. Similarity transformations are utilized to reduce the governing partial differential equations into a set of nonlinear ordinary differential equations. The reduced equations are numerically solved using Runge-Kutta-Fehlberg fourth-fifth order method along with shooting technique. The impact of several existing physical parameters on velocity, temperature, solutal and nanofluid concentration profiles are analyzed through graphs and tables in detail. It is found that, modified Dufour parameter and Dufour solutal Lewis number enhances the temperature and solutal concentration profiles respectively.
By means of small wind turbines, it is possible to create distributed sources of electricity useful in areas with good wind conditions. Sometimes, however, it is possible to use small wind turbines also in areas characterized by lower average wind speeds during the year. At the small wind turbine design stage, various types of technical solutions to increase the speed of the wind stream, as well as to optimally orientate it, can be applied. The methods for increasing the efficiency of wind energy conversion into electricity in the case of a wind turbine include: the use of a diffuser shielding the turbine rotor and the optimization of blades mounted on the turbine rotor. In the paper, the influence of the diffuser and rotor blades geometry on the efficiency of an exemplary wind turbine for exploitation in the West Pomeranian Province is investigated. The analyses are performed for three types of the diffuser and for three types of rotor blades. Based on them, the most optimal shapes of the diffuser and blades are selected due to the efficiency of the wind turbine. For the turbine with the designed diffuser, calculations of the output power for the assumed different values of the average annual wind speed and the constant Betz power factor and the specified generator efficiency are made. In all the analyzed cases, the amount of energy that can be generated by the turbine during the year is also estimated. Important practical conclusions are formulated on the basis of these calculations. In the final part of the paper, a 3D model of the wind turbine with the diffuser and rotor blades chosen based on earlier analyses is presented. As a material for the diffuser and rotor blades, glass fiber type A is applied. By means of calculations using the finite element method, the limit displacement of the turbine structure under the influence of a hurricane wind are determined. Based on these calculations, the correctness of the modelled small wind turbine structure has been demonstrated.
One of the most effective designs to control the road traffic noise is the T-shaped barrier. The aim of this study was to examine the performance of T-shape noise barriers covered with oblique diffusers using boundary element method. A 2D simulation technique based on the boundary element method (BEM) was used to compute the insertion loss at the center frequency of each one-third octave band. In designed barriers, the top surface of the T-shaped noise barriers was covered with oblique diffusers. The width and height of the barrier stem and the width of its cap were 0.3, 2.7, and 1 m, respectively. Angles of he oblique diffusers were 15, 30, and 45 degrees. The oblique diffusers were placed on the top surface with two designs including same oblique diffusers (SOD) and quadratic residue oblique diffusers (QROD). Barriers considered were made of concrete, an acoustically rigid material. The barrier with characteristics of QROD, forward direction, and sequence of angles (15, 30, and 45 degrees) had the greatest value of the overall A-weighted insertion loss equal to 18.3 to 21.8 dBA at a distance of 20 m with various heights of 0 to 6 m.
A modified emulsion polymerisation synthesis route for preparing highly dispersed cationic polystyrene (PS) nanoparticles is reported. The combined use of 2,2′-azobis[2-(2-imidazolin- 2-yl)propane] di-hydrochloride (VA-044) as the initiator and acetone/water as the solvent medium afforded successful synthesis of cationic PS particles as small as 31 nm in diameter. A formation mechanism for the preparation of PS nanoparticles was proposed, whereby the occurrence of rapid acetone diffusion caused spontaneous rupture of emulsion droplets into smaller droplets. Additionally, acetone helped to reduce the surface tension and increase the solubility of styrene, thus inhibiting aggregation and coagulation among the particles. In contrast, VA-044 initiator could effectively regulate the stability of the PS nanoparticles including both the surface charge and size. Other reaction parameters i.e. VA-044 concentration and reaction time were examined to establish the optimum polymerisation conditions.
Sound diffusers, in particular those based on changes in the phase of the reflected wave (Schroeder diffusers), have recently gained greatly in popularity in acoustics as an effective means to eliminate defects and improve the acoustic performance of interiors. This paper draws attention to a possibility of shaping acoustic parameters of sound diffusers and fundamental errors made in applying diffusers. Also, an often neglected issue of sound absorption by diffusers has been tackled. The presented results of laboratory measurements indicate a great significance of the diffusers' rigidity and geometry on their absorption coefficient at low frequencies. The effect of arrangement of elements on the diffusion coefficient was analysed for two types of elements based on the prime number N = 7.
This paper presents an approximate analytical model for estimating the transmission loss (TL) of a finite rectangular plate in the low frequency range, which is based on the modal summation approach (MSA) taking into account the modal radiation impedance and fluid loading. The mode-dependent radiation resistance is calculated using the Rayleigh integral. The fluid loading is taken into account through the natural frequency modified by the added mass. The results are compared with the ones of Statistical Energy Analysis (SEA) coupled with FEM and FEM coupled with BEM. In addition, the effects of the various vibration modes and the fluid loading on TL, and a way for reducing the calculation time are discussed.
The nonlinear interaction of wave and non-wave modes in a gas planar flow are considered. Attention is mainly paid to the case when one sound mode is dominant and excites the counter-propagating sound mode and the entropy mode. The modes are determined by links between perturbations of pressure, density, and fluid velocity. This definition follows from the linear conservation equations in the differential form and thermodynamic equations of state. The leading order system of coupling equations for interacting modes is derived. It consists of diffusion inhomogeneous equations. The main aim of this study is to identify the principle features of the interaction and to establish individual contributions of attenuation (mechanical and thermal attenuation) in the solution to the system.
Transport properties of bronchial mucus are investigated by two-stage experimental approach focused on: (a) rheological properties and (b) mass transfer rate through the stagnant layer of solutions of mucus components (mucine, DNA, proteins) and simulated multi-component mucus. Studies were done using thermostated horizontal diffusion cells with sodium cromoglycate and carminic acid as transferred solutes. Rheological properties of tested liquids was studied by a rotational viscometer and a cone-plate rheometer (dynamic method). First part of the studies demonstrated that inter-molecular interactions in these complex liquids influence both rheological and permeability characteristics. Transfer rate is governed not only by mucus composition and concentration but also by hydrophobic/hydrophilic properties of transported molecules. Second part was focused on the properties of such a layer in presence of selected nanostructured particles (different nanoclays and graphene oxide) which may be present in lungs after inhalation. It was shown that most of such particles increase visco-elasticity of the mucus and reduce the rate of mass transfer of model drugs. Measured effects may have adverse impact on health, since they will reduce mucociliary clearance in vivo and slow down drug penetration to the bronchial epithelium during inhalation therapy.
The article presents theoretical values of reverberation times calculated on the basis of the diffusion equation for three room models: flat, cubic, and long. The article shows that not only the average absorption coefficient, but also location of the absorbent material, as well as the place where the time is counted have an impact on the reverberation time, calculated on the basis of the diffusion equation. Despite that, the diffusion model is based on statistical assumptions. The primary goal of the article was to show that the model has geometrical features.
The work concerns the dynamic behaviour of a porous, isothermal catalyst pellet in which a simultaneous chemical reaction, diffusion and adsorption take place. The impact of the reactant adsorption onto the pellet dynamics was evaluated. A linear isotherm and a non-linear Freundlich isotherm were considered. Responses of the pellet to sinusoidal variations of the reactant concentration in a bulk gas were examined. It was demonstrated that the dynamics of the pellet is significantly affected both by accounting for the adsorption and by the frequency of the bulk concentration variations. The sorption phenomenon causes damping of the concentration oscillations inside the pellet and damping of its effectiveness factor oscillations. Depending on the frequency of the concentration oscillations in the bulk, the remarkable oscillations can involve an entire volume of the pellet or its portion in the vicinity of the external surface.
The objective of the research in this work was the modification of structure of carbide-type chromized layers, by the combination of diffusion chromizing with subsequent PVD treatment, consisting of chromium nitride deposition, carried out to improve their tribological properties. As a result, hybrid layers on the surface of tool steel were obtained. For comparison, the properties of single chromized carbide layers obtained in a diffusion chromizing process were tested. Investigations of layer microstructure, their mechanical properties, surface topography, adhesion of layers to the steel substrate, as well as tribological properties were conducted. The layer microstructure was characterized by X-ray diffraction and scanning electron microscopy. Topography of the layer surface was studied by an optical profilometer. The scratch test for investigations of layers adhesion to the steel substrate was used. Testing of tribological properties (linear wear) of the layers was performed by the three-cylinder-cone method. It was shown, that hybrid layers are characterized by a significantly smaller surface roughness than that of chromized carbide layers and their wear resistance improved almost twice with respect to carbide layers.
The article presents the method to assess the diffusion coefficient D in the sub-layer of intermetallic phases formed during hot-dip galvanizing “Armco” iron and ductile cast iron EN-GJS-500-7. Hot-dip galvanizing is one of the most popular forms of long-term protection of Fe-C alloys against corrosion. The process for producing a protective layer of sufficient quality is closely related to diffusion of atoms of zinc and iron. The simulation consist in performed a hot-dip galvanizing in laboratory condition above Fe-C alloys, in the Department of Engineering of Cast Alloys and Composites. Galvanizing time ranged from 15 to 300 seconds. Then metallographic specimens were prepared, intermetallic layers were measured and diffusion coefficient (D) were calculated. It was found that the diffusion coefficient obtained during hot-dip galvanizing “Armco” iron and zinc is about two orders of magnitude less than the coefficient obtained on ductile cast iron EN-GJS-500-7.
One of the methods to prevent unsuitable lubrication of moving components of devices and machinery is using bi-metal and three-metal bearings. Centrifugal casting process is one of the manufacturing methods that is used for such bearings. In this study, the purpose is microstructure evaluation of the bonding location and length determination of diffusion bond in structural steel-bronze. A mold made of structural steel with inner diameter of 240mm, length of 300mm and thickness of 10mm was coated by a 6mm film of bronze under centrifugal casting process. At first, a bronze ingot with dimension of 5mm×10mm×20mm is located inside of the hollow cylindrical mold and then the two ends of it will be sealed. During mold rotation with the rate of 800 rpm, two high power flames are used for heating the mold under Ar gas atmosphere to melt the bronze ingot at 1000˚C. After 15minutes, the system is cooled rapidly. Results showed that the diffusion bonding of bronze in structural steel to depth of 1.2µm from the bonding line was obtained. In this bonding, copper element was diffused to 50% of its initial concentration.
News might trigger jump arrivals in financial time series. The “bad” news and “good” news seem to have distinct impact. In the research, a double exponential jump distribution is applied to model downward and upward jumps. Bayesian double exponential jump-diffusion model is proposed. Theorems stated in the paper enable estimation of the model’s parameters, detection of jumps and analysis of jump frequency. The methodology, founded upon the idea of latent variables, is illustrated with simulated data.
In the present work the results of the investigations on dead zone formation conditions in catalyst pellet are discussed. A new, simple method of determining the types of kinetic equations for which such a zone can appear was developed on the basis of simple mathematical transformations. It was shown that: (i) pellet geometry has no influence on necessary conditions of the origination of dead zone (ii) only driving-force term (in the sense of Langmuir-Hinshelwood-Hougen-Watson kinetic approach) decides if a dead zone is formed. A new algorithm which allows fast and precise evaluation of critical Thiele modulus Fcrit (in a catalyst pellet for F>Fcrit the dead zone appears) was proposed and tested.
The aim of the present work is to verify a numerical implementation of a binary fluid, heat conduction dominated solidification model with a novel semi-analytical solution to the heat diffusion equation. The semi-analytical solution put forward by Chakaraborty and Dutta (2002) is extended by taking into account variable in the mushy region solid/liquid mixture heat conduction coefficient. Subsequently, the range in which the extended semi-analytical solution can be used to verify numerical solutions is investigated and determined. It has been found that linearization introduced to analytically integrate the heat diffusion equation impairs its ability to predict solidus and liquidus line positions whenever the magnitude of latent heat of fusion exceeds a certain value.
The investigations deal with mass transfer in simulated biomedical systems. The modification of classical diffusion chamber, sequential unit (SU) system, imitated different biomedical setups, boundary conditions. The experiments simulated: diffusion chamber (also with two barriers), transport through the membrane to the blood stream, transport from the stent eluting drug simultaneously to the vessel cells and to the blood stream. The concentrations of substances and the relative mass increases/decreases for SU systems indicate that the order of the curves follows the order of mass transfer resistances. The strong dependence of mass transfer rates versus type of diffusing substance was confirmed. The calculated drug fluxes, diffusion coefficients, permeation coefficients are convergent with literature. Permeation coefficients for complex sequential systems can be estimated as parallel connexion of constituent coefficients. Experiments approved functionality of the SU for investigations in a simulated biomedical system. Obtained data were used for numerical verification.
The paper presents the new solution to a road acoustic screen consisting of elements which are highly diffusing and simultaneously resistant to weathering, but also characterised by a sound absorption. There is described the comprehensive research of such the road acoustic screen with absorbing and diffusing surface. The study includes screen’s resistance to wind load and snow removal, impact tests and mea- surements of some acoustic parameters
The objective of the present research is to develop the novel multi-compaction technology to produce hybrid structure in powder metallurgy (P/M) components using dissimilar Fe-based alloys. Two distinct powder alloys with different compositions were are used in this study: Fe-Cr-Mo-C pre-alloyed powder for high strength and Fe-Cu-C mixed powder for enhanced machinability and lower material cost. Initially, Fe-Cu-C was pre-compacted using a bar-shaped die with lower compaction pressure. The green compact of Fe-Cu-C alloy was inserted into a die residing a half of the die, and another half of the die was filled with the Fe-Cr-Mo-C powder. Then they subsequently underwent re-compaction with higher pressure. The final compact was sintered at 1120°C for 60 min. In order to determine the mechanical behavior, transverse rupture strength (TRS) and Vickers hardness of sintered materials were measured and correlated with density variations. The microstructure was characterized using optical microscope and scanning electron microscope to investigate the interfacial characteristics between dissimilar P/M alloys.
Electronic Double-Layer Capacitors (EDLC), called Supercapacitors (SC), are electronic devices that are capable to store a relatively high amount of energy in a small volume comparing to other types of capacitors. They are composed of an activated carbon layer and electrolyte solution. The charge is stored on electrodes, forming the Helmholtz layer, and in electrolyte. The capacitance of supercapacitor is voltage- dependent. We propose an experimental method, based on monitoring of charging and discharging a supercapacitor, which enables to evaluate the charge in an SC structure as well as the Capacitance-Voltage (C-V) dependence. The measurement setup, method and experimental results of charging/discharging commercially available supercapacitors in various voltage and current conditions are presented. The total charge stored in an SC structure is proportional to the square of voltage at SC electrodes while the charge on electrodes increases linearly with the voltage on SC electrodes. The Helmholtz capacitance increases linearly with the voltage bias while a sublinear increase of total capacitance was found. The voltage on SC increases after the discharge of electrodes due to diffusion of charges from the electrolyte to the electrodes. We have found that the recovery voltage value is linearly proportional to the initial bias voltage value.
This project aimed to isolate and characterize volcanic soil Actinobacteria from Deception Island, Antarctic. A total of twenty−four Actinobacteria strains were isolated using four different isolation media (Starch casein agar, R2 agar, Actinomycete isolation agar, Streptomyces agar) and characterized basing on 16S rRNA gene sequences. Tests for secondary metabolites were performed using well diffusion method to detect antimicrobial activities against eight different pathogens, namely Staphyloccocus aureus ATCC 33591, Bacillus megaterium , Enterobacter cloacae , Klebsiella oxytoca , S. enterica serotype Enteritidis, S. enterica serotype Paratyphi ATCC 9150, S. enterica serotype Typhimurium ATCC 14028 and Vibrio cholerae . Antimicrobial properties were detected against Salmonella paratyphi A and Salmonella typhimurium at the concentration of 0.3092±0.08 g/ml. The bioactive strains were identified as Gordonia terrae , Leifsonia soli and Terrabacter lapilli. Results from this study showed that the soil of Deception Island is likely a good source of isolation for Actinobacteria. The volcanic soil Actinobacteria are potentially rich source for discovery of antimicrobial compounds.