This paper deals with computer modelling of the retention of a synthetic diamond particle in a metallic matrix produced by powder metallurgy. The analyzed sintered powders can be used as matrices for diamond impregnated tools. First, the behaviour of sintered cobalt powder was analyzed. The model of a diamond particle embedded in a metallic matrix was created using Abaqus software. The preliminary analysis was performed to determine the mechanical parameters that are independent of the shape of the crystal. The calculation results were compared with the experimental data. Next, sintered specimens obtained from two commercially available powder mixtures were studied. The aim of the investigations was to determine the influence of the mechanical and thermal parameters of the matrix materials on their retentive properties. The analysis indicated the mechanical parameters that are responsible for the retention of diamond particles in a matrix. These mechanical variables have been: the elastic energy of particle, the elastic energy of matrix and the radius of plastic zone around particle.
Ag and Cu powders were mechanically alloyed using high-energy planetary milling to evaluate the sinter-bonding characteristics of a die-attach paste containing particles of these two representative conductive metals mixed at atomic scale. This resulted in the formation of completely alloyed Ag-40Cu particles of 9.5 µm average size after 3 h. The alloyed particles exhibited antioxidation properties during heating to 225°C in air; the combination of high pressure and long bonding time at 225°C enhanced the shear strength of the chip bonded using the particles. Consequently, the chips sinter-bonded at 225°C and 10 MPa for 10 min exhibited a sufficient strength of 15.3 MPa. However, an increase in bonding temperature to 250°C was detrimental to the strength, due to excessive oxidation of the alloyed particles. The mechanically alloyed phase in the particle began to decompose into nanoscale Ag and Cu phases above a bonding temperature of 225°C during heating.
In this paper are presented results of study fusion characteristics of the biomass ashes from the hydrolyzed lignin and the ashes from the coke breeze. The hydrolyzed lignin ashes were compared with the coke breeze ashes i.e. with a fossil fuel. These ashes were prepared in muffle furnace at the temperature of 550°C (hydrolyzed lignin) and 850°C (coke breeze). Biomass (the hydrolyzed lignin) represents the new fuels for sintering process and an attractive way to decrease CO2 emissions from the energy production. The characterization methods were the following: standard fuel characterization analyses, chemical and mineralogical composition of the ashes and phase analyses of the ashes of biomass and the coke breeze. These ashes were prepared by the same method. Characterisation of the ashes samples was conducted by means of X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Quantitative analysis of the crystalline and amorphous phases in each of the ash samples were carried out using the Rietveld method. The dominant phase of the ash from the coke breeze was mullite (Al6Si2O13). SiO2 is the dominant phase of the ash from the hydrolyzed lignin.